MICROCAT® CATALYSTS
The use of Microcat catalysts in lead-acid applications allows the use of less pure lead without degraded performance. The Microcat poison filter is formulated to prevent contamination from amines, stibines, arsines and hydrogen sulfide. Without poison filtration, catalysts will more rapidly decline in capacity and efficiency over time.
Battery Technology | VRLA Battery
Part no. | CTL-064, CTL-090
Significant Reduction in Float Current
One of the most immediate benefits of the catalyst is a significant drop in float current, typically to half or less. This reduction occurs because the catalyst helps re-polarize the negative plate, preventing it from discharging due to excess oxygen. Less current being drawn by the cell means less energy wasted. This directly translates into energy savings and a crucial reduction in cell heating, easing the burden on cooling HVAC systems and maintaining a cooler operating environment for all nearby electronics.
Extended Longevity
The Microcat Catalyst actively combats the primary causes of battery failure to increase the cell and battery life. By reducing the float current, it minimises positive plate corrosion and grid damage, which is the foundational limit of a lead-acid cell's design life. Furthermore, it helps maintain cell capacity by preventing negative plate depolarization, allowing the cell to pass capacity tests and remain healthy for longer consistently.
Enhanced Safety
By efficiently recombining hydrogen and oxygen gases back into water inside the cell, the technology minimizes water loss, solving the predominant cause of customer dissatisfaction and failure, particularly with VRLA cells. This internal process not only preserves the electrolyte but also significantly reduces heating and current flow, minimizing the risk of thermal runaway, a critical safety feature that ensures the long-term reliability of your reserve power system.
The unique Microcat® design
Works by consuming free oxygen in the headspace of the cell.
Performance Data
Premium quality cells show marked performance differences when tested on float in our labs, as the following graphs show:
Figure 1. Influence of catalysts on float current at 2.27 V/cell and 90°F (32°C).
Figure 2. Comparison of gassing rates of standard cells versus catalyst cells at 90°F (32°C), showing an increase in theoretical service life.
Why MicroCat Catalyst
Reduced Float Current
A Microcat catalyst provides an immediate and observable drop in the float current, leading to a reduction in water loss, positive plate corrosion, cell temperature and energy usage and costs.
Longer Life
A cell installed with a catalyst will last up to 40% longer.
Improved Cell
A Microcat can lead to significant capacity increases.
Increased Profitability
Money which would have been spent on replacing or repairing batteries can be invested more profitably elsewhere.
|
Benefits |
Microcat Catalysts |
|
|---|---|---|
| Reduction in Float Current | ||
| Increased Cell & Battery Life | ||
| Minimized Water Loss | ||
| Maintained Cell Capacity | ||
| Minimized Positive Plate Corrosion | ||
| Reduced Cell Heating | ||
| Reduced Risk of Thermal Runaway | ||
| Energy Savings | ||
Reduction in Float Current
One of the most immediate, observable effects of installing a catalyst in a VRLA cell is a sudden drop in the float current. Typically, float currents are one half or less when a catalyst is installed. In a VRLA cell, the negative plate does double duty compared with a flooded cell. In addition to normal negative plate functions, it is also where oxygen and hydrogen are recombined into water, making the cell maintenance free.
When this process is too efficient, excess oxygen reaching the negative plate causes it to become depolarized. When the negative plate is depolarized, the charging system will supply more current in an effort to bring the cell voltage up. The additional current becomes excessive overcharge on the positive plate, which has many damaging effects on the cell.
Adding a Microcat catalyst to the cell prevents some of the oxygen from reaching the negative plate and allows the negative plate to stay polarized. This means that less current needs to be supplied to the cell from the charging system, manifesting itself as lower float current.
Increased Cell & Battery Life
VRLA cells have many potential failure modes. A number of these failure modes can be mitigated by the catalyst technology – failure modes such as cell dry-out; positive plate, grid and strap corrosion; thermal runaway; and capacity loss due to negative plate depolarization.
Employment of a Microcat catalyst will lessen the occurrence and impact of these failure modes, thereby increasing the working life of the cell and the battery.
Minimized Water Loss
Hydrogen and oxygen gases are recombined into water by the Microcat catalyst inside the cell rather than exiting the cell.
Too much of these gases leaving the cell can lead to premature dry-out and cell failure. Cell dry-out has been the predominant cause of customer dissatisfaction with VRLA technology.
Maintained Cell Capacity
Many VRLA cells in service are failing capacity tests because their negative plates are depolarized.
In fact significant capacity increases have been seen on some cells just by installing a catalyst.
Minimized Positive Plate Corrosion
A reduction in float current reduces the amount of overcharge on the positive plate, which directly impacts the corrosion rate. The design life of a lead acid cell is based upon the corrosion of the plate, barring any other unforeseen failure modes.
Reduced Cell Heating
Any excess current above that needed to charge the cell is converted directly into heat. A reduction in float current means less heat produced. This can result in a cooler environment for batteries and electronics and a reduced load on HVAC systems.
Reduced Risk of Thermal Runaway
Since heating is reduced and float current minimized, there is less risk of thermal runaway.
Energy Savings
Reduced float current directly translates into less power purchased.
MicroCat Model Options
MicroCat for VRLA Block Batteries
Dimensions | 10.5mm (Diameter), 18mm (Height)
Colour | Blue
Attachment | Cover Mounted & Drop-In
Part no. | CTL-064
MicroCat for 2V VRLA
Dimensions | 15mm (Diameter), 20mm (Height)
Colour | Natural
Attachment | ClickFIT & Drop-in
Part no. | CTL-090
Technical Specifications
|
Recombination Rating |
17.1 +/- 5.7 cc/min H2 & O2 |
|
Max Internal Temperature |
93°C / 200°F |
|
Max External Temperature |
260°C / 500°F |
|
Body Materials |
Non-Hygroscopic, High-Impact & High-Temperature Polymer |
|
Typical Positive Polarization Shift |
+30 mV |
|
Typical Negative Polarization Shift |
-30 mV |
|
Dimensions |
CTL-064 CTL-090 |
Resources
Reference papers
Lead Purity: The Mother of All VRLA Problems - 2010 Battcon paper
The paper discusses the fundamental problem in VRLA batteries of using impure/recycled lead. Catalysts can solve this problem by accommodating the excess internal gassing caused by the impure lead...Read More
Monobloc Batteries, High Temperatures & Catalysts - 2006 Battcon Paper
Outside plant and other high ambient temperature applications are dramatically reducing the life of 12V monobloc batteries. The use of an internal catalyst is discussed to increase the life and help mitigate the detrimental effects of this temperature...Read More
A Case Study: Four Years of Test Data - Infobatt 2004 paper
This presentation offers the results of rehydration and catalyst addition to a 48 volt, VRLA battery string. Data was accumulated over 4 years with a verification of performance during the August 2003 blackout. Click here for presentation...Read More
Advances in the Design and Application of Catalysts
This paper discusses advanced in the design of the internal catalyst for batteries. One area of focus is the development and design of a catalyst that can accommodate hydrogen sulfide. This gas is normally found within the lead-acid system, and can be a poison to catalysts. Click here for presentation...Read More
Catalyst 201: Catalysts and Poisons from the Battery
This paper presents the early discovery of hydrogen sulfide within the lead-acid battery. Long term tests to confirm this discovery as well as a preliminary design to prevent this gas from poisoning the catalyst are presented...Read More
Catalysts 101: The Basics of using Catalysts in VRLA cells
This paper summaries five (5) years of focused work on catalyst function and operation within a battery system. Polarizations of the electrodes are discussed and the demonstrated improvements from internal catalysts...Read More
Hydrogen Sulfide in VRLA Cells
This paper presents the initial work regarding hydrogen sulfide generation within the lead-acid battery system. The creation and absorption of this gas within the battery is discussed in the context of a 'hydrogen sulfide cycle'...Read More
Quantifying Secondary Reactions in VRLA Batteries
This paper discusses the impurities found in lead-acid battery materials, and how these impurities can affect negative plate discharge, and discusses cell balancing necessary for long-life, VRLA battery design...Read More
Balanced Float Charging of VRLA Batteries by Means of Catalysts
This paper discusses the internal oxygen cycle within the lead-acid battery system and the relationship between electrode polarization, recombination efficiency and the role of the catalyst in this scenario...Read More
Can VRLA Batteries Last 20 years?
This paper provides experimental data on the discharging of the negative plate during steady-state float charging, per the manufacturer's recommendations. The positive effects of an internal catalyst are presented in terms of extending the life of VRLA batteries...Read More
Correcting Inherent Imbalance and Consequent Failure of VRLA
Experimental data is presented to reveal how chemical imbalance within the VRLA battery system can shorted life through negative plate discharge and water loss...Read More
Gas Evolution, Dryout, and Lifetime of VRLA Batteries - An Attemin' to Clarify Fifteen Years of Confusion and Misunderstanding
This paper presents a summary of experimental data and studies that confirm the vulnerability of VRLA batteries to shortened lifetimes through unplanned water loss...Read More
Behavior of VRLA cells on Long Term Float: Part 2
Experimental laboratory data is presented that compared the operation of VRLA batteries both with and without an internal catalyst. A confirmation of the benefits of catalysts is presented...Read More
Float Behavior of VRLA Cells: Theory v.s. Reality
Experimental data on 20 year design life VRLA batteries is presented with a focus on the water consumption during normal operation. A discussion of the internal chemical operation is presented....Read More
Related Products
CatVent Catalyst
Designed explicitly for flooded/vented cells in stationary battery applications.
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